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Guan Yu and Zhang Fei were high school students, but due to their excessive love for upholding justice, they were expelled from twenty-four schools, earning them the nickname "The Twenty-Four Schools!" Just as they felt utterly hopeless after yet another expulsion, a man with large earlobes suddenly appeared. He introduced himself as Liu Bei, styled Xuande, a member of a fallen noble family who frequently changed schools because he couldn't afford the tuition fees. Liu Bei proposed a plan: since he had noble bloodlines, he could attend the best aristocratic school in the country, the "Eastern Han Academy." However, this school was so expensive that only royal relatives or nobles could afford it. Zhang Fei, being wealthy, offered to pay the tuition fees for everyone. Liu Bei said that as long as the money issue was resolved, everything else could be arranged. He suggested that the three of them swear brotherhood, making them all royal relatives and thus eligible to enroll in the academy. Delighted by the idea, the trio found a meaningful and picturesque place to take their oath.

Just as they finished their vow—"We do not seek to be born on the same day, month, and year, but we wish to die on the same day, month, and year"—four people, Xiu, Wang Dadaong, Ding Xiaoyu, and Wang Yasser, traveled through a time portal from the Iron Space-Time to Silver Space-Time. Unfortunately, Dadaong accidentally dropped a coin, which knocked over an empty can, starting a chain reaction that eventually caused a rock to fall and strike Liu Bei, killing him instantly. Guan Yu, bound by his promise to follow his elder brother until death, was determined to join Liu Bei in death. Zhang Fei tried to stop him and managed to knock Guan Yu unconscious. To everyone's relief, Liu Bei wasn't dead, just severely injured and unconscious. After consulting with Dadaong, Xiaoyu, and Yasser, they decided to leave Xiu in Silver Space-Time as a substitute for Liu Bei (since Xiu's counterpart in Silver Space-Time was Liu Bei). Despite his reluctance, Xiu agreed to maintain the space-time order. Meanwhile, the others took the seriously wounded Liu Bei back to Gold Space-Time for treatment.

When Guan Yu woke up and discovered that Xiu, posing as Liu Bei, was alive, he was overjoyed. Zhang Fei was also glad that they wouldn't have to die together. The three finally entered the Eastern Han Academy, where Guan Yu and Zhang Fei believed they would make a name for themselves. They hoped to graduate peacefully, but the Eastern Han Academy, being well-known, attracted trouble from the Yellow Turban High School and River East High School (where Dong Zhuo was the principal), putting the academy constantly in danger. Master Zuo Ci even set up the 'Eight Gates Golden Lock Formation' at the school gate to prevent students from attending classes. Naturally, the trio took it upon themselves to break the formation. However, breaking the Eight Gates Golden Lock Formation wasn't easy, and both Liu Bei (Xiu) and Xiao Qiao were trapped inside, facing life-threatening dangers. Following the advice of the Student Union President Cao Cao, Guan Yu and Zhang Fei sought help from Ma Chao, an extremely resilient and cheerful young man, and his good friend Huang Zhong, an infallible archer. Additionally, Zhao Yun, a super handsome youth who had always been at odds with them, joined forces with them to break the formation and rescue Liu Bei (Xiu) and Xiao Qiao.

During the process of breaking the formation, Guan Yu saved Zhao Yun's life by blocking an arrow with his arm during a critical moment, resolving the previous animosity between Zhao Yun and the other two. Zhao Yun then swore brotherhood with the other four, forming a bond of trust and mutual support, and together they successfully broke the Eight Gates Golden Lock Formation.

After breaking the formation and gaining new brothers, they thought they could finish high school smoothly. However, on one side, the Yellow Turban High School was lurking, wanting to seize the resources of the Eastern Han Academy. On the other side, Dong Zhuo, the principal of River East High School, Cao Cao, the student union president of Eastern Han, and Yuan Shao, the leader of the Guandong School Alliance, all coveted the throne of the Young Emperor of the 'Alliance of All Schools,' ensuring that Liu Bei and the Five Tigers could never live a peaceful campus life. A battle for supremacy was about to begin...